Guest editorial: Structural seismic safety assessment     

Carlos Sousa Oliveira  Aníbal Costa  Raimundo Delgado 《Bulletin of Earthquake Engineering》2010,8(1):1-3

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The scope for generating bio-oils with relatively low oxygen contents via hydropyrolysis   总被引：3，自引：0，他引：3  

J. Dilcio Rocha  Carlos A. Luengo  Colin E. Snape   《Organic Geochemistry》1999,30(12):1599

The primary oils obtained in high yields from fast (fluidised-bed) pyrolysis of biomass generally have high oxygen contents (ca. 40% w/w). The scope for using pyrolysis under hydrogen pressure (hydropyrolysis), to give oils with much lower oxygen contents compared to normal pyrolysis has been investigated. Fixed-bed hydropyrolysis tests have been conducted on cellulose, sugar cane bagasse and eucalyptus wood using hydrogen pressures up to 10 MPa, with heating rates of 5 and 300°C min⁻¹. A colloidal FeS catalyst was used in some tests (Fe loading of 5%, w/w) to increase overall conversions. Further, the attractive option of using a two-stage reactor in which the primary oil vapors are passed though a bed of hydrotreating catalyst is also described. Raising the hydrogen pressure from atmospheric to 10 MPa reduced the oxygen content of the primary oil by over 10% to below 20% w/w. The addition of a dispersed iron sulphide catalyst gave conversions close to 100% for all three biomass samples investigated at 10 MPa under conditions in the fixed-bed reactor where significant diffusional resistances existed and reduced the oxygen content of the bio-oil by a further 10%. Although NMR indicated that the oils became increasingly aromatic as more oxygen was removed, the increase in hydrogen pressure decreased the extent of overall aromatisation that occurs primarily due to the lower char yields obtained. In two-stage tests for cellulose, using a commercial sulphided Ni/Mo γ-Al₂O₃ catalyst at 400°C, increasing the hydrogen pressure from 2.5 to 10 MPa decreased the oxygen content of the oil by over 20% to 10% w/w. The H/C ratios were higher and O/C ratios smaller for the two-stage bio-oils compared to their single stage counterparts. However, the differences in the O/C ratios between the single and two-stage bio-oils increase with pressure.  相似文献   

Phenological Changes of Blooming Diatoms Promoted by Compound Bottom-Up and Top-Down Controls     

Valeria A. Guinder  Juan Carlos Molinero  Celeste M. López Abbate  Anabela A. Berasategui  Cecilia A. Popovich  Carla V. Spetter  Jorge E. Marcovecchio  Rubén H. Freije 《Estuaries and Coasts》2017,40(1):95-104

Understanding phytoplankton species-specific responses to multiple biotic and abiotic stressors is fundamental to assess phenological and structural shifts at the community level. Here, we present the case of Thalassiosira curviseriata, a winter-blooming diatom in the Bahía Blanca Estuary, Argentina, which displayed a noticeable decrease in the past decade along with conspicuous changes in phenology. We compiled interannual field data to assess compound effects of environmental variations and grazing by the invasive copepod Eurytemora americana. The two species displayed opposite trends over the period examined. The diatom decreased toward the last years, mainly during the winters, and remained relatively constant over the other seasons, while the copepod increased toward the last years, with an occurrence restricted to winter and early spring. A quantitative assessment by structural equation modeling unveiled that the observed long-term trend of T. curviseriata resulted from the synergistic effects of environmental changes driven by water temperature, salinity, and grazing. These results suggest that the shift in the abundance distribution of T. curviseriata toward higher annual ranges of temperature and salinity—as displayed by habitat association curves—constitutes a functional response to avoid seasonal overlapping with its predator in late winters. The observed changes in the timing and abundance of the blooming species resulted in conspicuous shifts in primary production pulses. Our results provide insights on mechanistic processes shaping the phenology and structure of phytoplankton blooms.  相似文献   

Geochemical Indicators of Intrinsic Bioremediation   总被引：19，自引：0，他引：19  

Robert C. Borden  Carlos A. Gomez  Mark T. Becker 《Ground water》1995,33(2):180-189

A detailed field investigation has been completed at a gasoline-contaminated aquifer near Rocky Point, NC, to examine possible indicators of intrinsic bioremediation and identify factors that may significantly influence the rate and extent of bioremediation. The dissolved plume of benzene, toluene, ethylbenzene, and xylene (BTEX) in ground water is naturally degrading. Toluene and o-xylene are most rapidly degraded followed by m-, p-xylene, and benzene. Ethylbenzene appears to degrade very slowly under anaerobic conditions present in the center of the plume. The rate and extent of biodegradation appears to be strongly influenced by the type and quantity of electron acceptors present in the aquifer. At the upgradient edge of the plume, nitrate, ferric iron, and oxygen are used as terminal electron acceptors during hydrocarbon biodegradation. The equivalent of 40 to 50 mg/I of hydrocarbon is degraded based on the increase in dissolved CO₂ relative to background ground water. Immediately downgradient of the source area, sulfate and iron are the dominant electron acceptors. Toluene and o-xylene are rapidly removed in this region. Once the available oxygen, nitrate, and sulfate are consumed, biodegradation is limited and appears to be controlled by mixing and aerobic biodegradation at the plume fringes.  相似文献   

Estimating Buoyancy Heat Flux Using the Surface Renewal Technique over Four Amazonian Forest Sites in Brazil     

Marcelo Zeri  Leonardo D. A. Sá  Carlos A. Nobre 《Boundary-Layer Meteorology》2013,149(2):179-196

The surface renewal (SR) method was applied for the first time to measurements of air temperature over four Amazonian forest sites and different seasons in order to obtain estimates of buoyancy heat flux. The required calibration of this method against eddy covariance resulted in a value for a specific parameter that is close to the range reported in other studies, contributing to the generalization of the SR method to different kinds of canopies. The comparison with fluxes obtained using the eddy covariance technique revealed a good match between the two methods for different sites, heights and seasons. Sites with high levels of non-stationarity in the signals of temperature and wind speed presented higher scatter in the regression with fluxes from eddy covariance. For a particular site with previously reported influence of low-frequency motions, the regression was only satisfactory, i.e., slope parameter close to unity and small offset, when oscillations with periods longer than $\approx $ ≈ 13 min were filtered out. The SR method has a great potential due to the simplicity of the instrumentation required. However, care should be taken when measuring under the influence of mesoscale motions, which can lead to high levels of non-stationarity, compromising the fundamental concepts of the SR theory.  相似文献   

Structural framework and Mesozoic–Cenozoic evolution of Ponta Grossa Arch, Paraná Basin, southern Brazil     

Michael Strugale  Sidnei Pires Rostirolla  Fernando Mancini  Carlos Vieira Portela Filho  Francisco Jos Fonseca Ferreira  Rafael Corrêa de Freitas 《Journal of South American Earth Sciences》2007,24(2-4):203-227

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Plant diversity and community structure of Brazilian <Emphasis Type=\"Italic\">Páramos</Emphasis>     

Prímula Viana Campos  Pedro Manuel Villa  Jaquelina Alves Nunes  Carlos E.G.R. Schaefer  Stefan Porembski  Andreza Viana Neri 《山地科学学报》2018,15(6):1186-1198

In Eastern South America, high altitude grasslands represent a mountain system that has a high number of endemic species. However, studies on the ecology of plant communities in these environments remain scarce. We aimed to evaluate the patterns of biodiversity and structure of plant communities from rocky outcrops in high altitude grasslands of three areas at the Caparaó National Park, southeastern Brazil, by sampling 300 randomly distributed plots. Then, we compared the floristic composition, relative abundance, and biological and vegetation spectra among areas. We classified species as endemic and non-endemic and verified the occurrence of endangered species. Species richness was evaluated by rarefaction analysis on the sampling units. The importance value and species abundance distribution (SAD) models were assessed. We also performed an indicator species analysis. We sampled 58 species belonging to 49 genera and 32 families. The number of species decreased with increasing altitude, with significant differences being observed among areas regarding richness, abundance, and cover. Of the total number of species, 10 are endemic to the Caparaó National Park and 17 are listed on the Brazilian Red List of endangered species. The dominant families on all peaks were Asteraceae and Poaceae. The SAD models showed lognormal and geometric distributions, corroborating the fact that 10 species that were common to all three areas were also the most dominant ones in the communities and showed the highest importance values, which ranged between 35% and 60%. Indicator species analysis revealed that 28 species (48.27%) were indicators. Of these, 42.85% had maximum specificity, meaning that they occurred only in one area. Thus, the number of species per life form ratio was similar among areas, yet vegetation spectra differed, especially for hemicryptophytes. The altimetric difference among the areas showed to be a very important driver in the community assembly, influencing the evaluated variables, however, other drivers as soil depth, slope and water could also influence the community structure on a smaller and local spatial scale.  相似文献   

Galaxy destruction and diffuse light in clusters     

Carlos Calcáneo-Roldán  Ben Moore  Joss Bland-Hawthorn  David Malin  Elaine M. Sadler 《Monthly notices of the Royal Astronomical Society》2000,314(2):324-333

Deep images of the Centaurus and Coma clusters reveal two spectacular arcs of diffuse light that stretch for over 100 kpc, yet are just a few kiloparsecs wide. At a surface brightness of m _b ∼27–28 mag arcsec⁻² , the Centaurus arc is the most striking example known of structure in the diffuse light component of a rich galaxy cluster. We use numerical simulations to show that the Centaurus feature can be reproduced by the tidal debris of a spiral galaxy that has been tidally disrupted by the gravitational potential of NGC 4709. The surface brightness and narrow dimensions of the diffuse light suggest that the disc was corotating with its orbital path past pericentre. Features this prominent in clusters will be relatively rare, although at fainter surface brightness levels the diffuse light will reveal a wealth of structure. Deeper imaging surveys may be able to trace this feature for several times its presently observed extent, and somewhere along the tidal debris, a fraction of the original stellar component of the disc will remain bound, but transformed into a faint spheroidal galaxy. It should be possible to confirm the galactic origin of the Centaurus arc by observing planetary nebulae along its length with redshifts close to that of NGC 4709.  相似文献   

时间延迟对劈裂试验条件下岩石凯塞效应的影响   总被引：1，自引：0，他引：1  

谢强  余贤斌 《岩土力学》2010,31(1):46-50

验证了粗晶花岗岩在劈裂试验条件下凯塞效应的存在性。进行了循环加卸载时间间隔分别为2、15d和45d时岩石的声发射试验,讨论了时间延迟对花岗岩凯塞效应的影响。研究结果表明,前期荷载越接近极限强度,岩石的凯塞效应越不明显;凯塞效应随再次加载时间延迟的增加而削弱,在对花岗岩的声发射试验中观察到15d以后岩石的凯塞效应仍然很显著,45d后凯塞效应基本消失。文中同时对试件与加载设备之间的接触状态对声发射试验结果的影响作了初步的定性分析。  相似文献   

    

SOTO Víctor  WELSH R. Carlos M.  YOSHIKAWA Kenji  DELGADO GRANADOS Hugo 《山地科学学报》2024,43(6):1954-1977

The glacial history of Pico de Orizaba indicates that during the Last Glacial Maximum, its icecap covered up to ~3000 m asl; due to the air temperature increasing, its main glacier has retreated to 5050 m asl. The retraction of the glacier has left behind an intense climatic instability that causes a high frequency of freeze-thaw cycles of great intensity; the resulting geomorphological processes are represented by the fragmentation of the bedrock that occupies the upper parts of the mountain. There is a notable lack of studies regarding the fragmentation and erosion occurring in tropical high mountains, and the associated geomorphological risks; for this reason, as a first stage of future continuous research, this study analyzes the freezing and thawing cycles that occur above 4000 m asl, through continuous monitoring of surface ground temperature. The results allow us to identify and characterize four zones: glacial, paraglacial, periglacial and proglacial. It was found that the paraglacial zone presents an intense drop of temperature, of up to ~9℃ in only sixty minutes. The rock fatigue and intense freeze-thaw cycles that occur in this area are responsible for the high rate of rock disintegration and represent the main factor of the constant slope dynamics that occur at the site. This activity decreases, both in frequency and intensity, according to the distance to the glacier, which is where the temperature presents a certain degree of stability, until reaching the proglacial zone, where cycles are almost non-existent, and therefore there is no gelifraction activity. The geomorphological processes have resulted in significant alterations to the mountain slopes, which can have severe consequences in terms of risk and water.  相似文献