Investigating the scale of structural controls on chlorinated hydrocarbon distributions in the fractured-porous unsaturated zone of a sandstone aquifer in the UK     

Adrian Lawrence  Marianne Stuart  Colin Cheney  Neil Jones  Richard Moss 《Hydrogeology Journal》2006,14(8):1470-1482

Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL).  相似文献   

Earth-moon relationships, edited by C. Barbieri and F. Rampazzi. Kluwer Academic Publishers, Dordrecht (Netherlands), 2001, 575 pp. Eur 229, GBP 140, US $199 (ISBN 0-7923-7089-9)     

Stuart Ross Taylor 《Geochimica et cosmochimica acta》2002,66(8):1495

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Comment on: 'The 3D shear experiment over the Natih field in Oman: the effects of fracture-filling fluids on shear propagation' by C.M. van der Kolk, W.S. Guest and J.H.H.M. Potters     

J.A. Hudson  Stuart Crampin 《Geophysical Prospecting》2003,51(4):365-368

We find errors in theory and application in the paper by van der Kolk et al. (Geophysical Prospecting 49 , 179–197 (2001)) that invalidate their arguments for the cause of the reduction in the velocity of the vertically propagating slower split shear-wave in the gas cap over the Natih field in Oman. We suggest that existing theories are adequate and can explain the anomaly.  相似文献   

Discrete-element modelling of detachment folding     

Stuart Hardy  Emma Finch† 《Basin Research》2005,17(4):507-520

A two‐dimensional, discrete‐element modelling technique is used to investigate the initiation and growth of detachment folds in sedimentary rocks above a weak décollement level. The model depicts the sedimentary rocks as an assemblage of spheres that obey Newton's equations of motion and that interact with elastic forces under the influence of gravity. Faulting or fracturing between neighbouring elements is represented by a transition from repulsive–attractive forces to solely repulsive forces. The sedimentary sequence is mechanically heterogeneous, consisting of intercalated layers of markedly different strengths and thicknesses. The interlayering of weak and strong layers within the sedimentary rocks promotes the localization of flexural flow deformation within the weak layers. Even with simple displacement boundary conditions, and straightforward interlayering of weak and strong layers, the structural geometries that develop are complex, with a combination of box, lift‐off and disharmonic detachment fold styles forming above the décollement. In detail, it is found that the modelled folds grow by both limb rotation and limb lengthening. The combination of these two mechanisms results in uplift patterns above the folds that are difficult, or misleading, to interpret in terms of simple kinematic models. Comparison of modelling results with natural examples and with kinematic models highlights the complexities of structural interpretation in such settings.  相似文献   

A numerical model of the partitioning of trace chemical solutes during drop freezing     

A. L. Stuart  M. Z. Jacobson 《Journal of Atmospheric Chemistry》2006,53(1):13-42

Partitioning of volatile chemicals among the gas, liquid, and solid phases during freezing of liquid water in clouds can impact trace chemical distributions in the troposphere and in precipitation. We describe here a numerical model of this partitioning during the freezing of a supercooled liquid drop. Our model includes the time-dependent calculation of the coupled processes of crystallization kinetics, heat transport, and solute mass transport, for a freezing hydrometeor particle. We demonstrate the model for tracer partitioning during the freezing of a 1000 μm radius drop on a 100 μm ice substrate, under a few ambient condition scenarios. The model effectively simulates particle freezing and solute transport, yielding results that are qualitatively and quantitatively consistent with previous experimental and theoretical work. Results suggest that the ice shell formation time is governed by heat loss to air and not by dendrite propagation, and that the location of ice nucleation is not important to freezing times or the effective partitioning of chemical solutes. Even for the case of nucleation at the center of the drop, we found that dendrites propagated rapidly to form surface ice. Freezing then proceeded from the outside in. Results also indicate that the solid-liquid interfacial surface area is not important to freezing times or the effective partitioning of chemical solutes, and that the rate aspects of trapping are more important than equilibrium solid-liquid partitioning to the effective partitioning resulting from freezing.  相似文献   

Emplacement of the Cabezo María lamproite volcano (Miocene,SE Spain)     

Thomas M. Gernon  Samuel Spence  Clive N. Trueman  Rex N. Taylor  Eelco Rohling  Stuart J. Hatter  Ian C. Harding 《Bulletin of Volcanology》2015,77(6):1-13

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Fire and vegetation shifts in the Americas at the vanguard of Paleoindian migration     

Nicholas Pinter  Stuart Fiedel  Jon E. Keeley 《Quaternary Science Reviews》2011,30(3-4):269-272

Across North and South America, the final millennia of the Pleistocene saw dramatic changes in climate, vegetation, fauna, fire regime, and other local and regional paleo-environmental characteristics. Rapid climate shifts following the Last Glacial Maximum (LGM) exerted a first-order influence, but abrupt post-glacial shifts in vegetation composition, vegetation structure, and fire regime also coincided with human arrival and transformative faunal extinctions in the Americas. We propose a model of post-glacial vegetation change in response to climatic drivers, punctuated by local fire regime shifts in response to megaherbivore-driven fuel changes and anthropogenic ignitions. The abrupt appearance of humans, disappearance of megaherbivores, and resulting changes in New World fire systems were transformative events that should not be dismissed in favor of climate-only interpretations of post-glacial paleo-environmental shifts in the Americas. Fire is a mechanism by which small human populations can have broad impacts, and growing evidence suggests that early anthropogenic influences on regional, even global, paleo-environments should be tested alongside other potential causal mechanisms.  相似文献   

Dams on the Mekong River: Lost fish protein and the implications for land and water resources     

Stuart Orr  Jamie Pittock  Ashok Chapagain  David Dumaresq 《Global Environmental Change》2012,22(4):925-932

Proposed dam construction in the Lower Mekong Basin will considerably reduce fish catch and place heightened demands on the resources necessary to replace lost protein and calories. Additional land and water required to replace lost fish protein with livestock products are modelled using land and water footprint methods. Two main scenarios cover projections of these increased demands and enable the specific impact from the main stem dam proposals to be considered in the context of basin-wide hydropower development. Scenario 1 models 11 main stem dams and estimates a 4–7% increase overall in water use for food production, with much higher estimations for countries entirely within the Basin: Cambodia (29–64%) and Laos (12–24%). Land increases run to a 13–27% increase. In scenario 2, covering another 77 dams planned in the Basin by 2030 and reservoir fisheries, projections are much higher: 6–17% for water, and 19–63% for land. These are first estimates of impacts of dam development on fisheries and will be strongly mediated by cultural and economic factors. The results suggest that basic food security is potentially at a high risk of disruption and therefore basin stakeholders should be fully engaged in strategies to offset these impacts.  相似文献   

Sampling the vertical particle flux in the upper water column using a large diameter free-drifting NetTrap adapted to an Indented Rotating Sphere sediment trap     

Michael L. Peterson  Joan Fabres  Stuart G. Wakeham  Cindy Lee  Ivn J. Alonso  Juan Carlos Miquel 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1547-1557

Further development of the large, surface-tethered sediment trap (NetTrap) employed as part of the MedFlux program is described whereby the large collection capacity of the NetTrap is combined with an Indented Rotating Sphere/Sample Carousel (IRSC) sediment trap (IRSC–NT). This trap is capable of collecting particle flux either in a time series or settling velocity mode; settling velocity mode allows the collection of particles that fall within discrete settling velocity intervals. During short field deployments in the Mediterranean Sea the IRSC–NT configured in the settling velocity mode successfully collected unpoisoned samples for chemical and microbiological experiments. In addition to the development of the IRSC–NT, particle-settling behavior above and below the swimmer-excluding IRS valve was tested during on-deck experiments using a specially constructed water-tight trap. Chemical analyses of settling materials (published elsewhere) suggested that separation of particles by settling velocity was achieved. However, due to the motion of the ship, it was not possible to directly measure particle-settling velocities within the trap. Particle release from the IRS did not bias the apparent settling velocity spectrum. Rotation of the IRS did not engender turbulence at the surface of the sphere or within the skewed funnel below. Tests of different ball designs over the course of the MedFlux program showed that a “ridge and saddle” pattern was optimal for efficiently transferring particles under the IRS seal while still reducing swimmer entrance to the collection funnel. The large size of the IRSC–NT did not prevent it from drifting effectively with the current. Several modifications of the present design are proposed that should improve the accuracy of the settling velocity measurements.  相似文献   

MedFlux: Investigations of particle flux in the Twilight Zone     

Cindy Lee  Robert A. Armstrong  J. Kirk Cochran  Anja Engel  Scott W. Fowler  Madeleine Goutx  Pere Masqu  Juan Carlos Miquel  Michael Peterson  Christian Tamburini  Stuart Wakeham 《Deep Sea Research Part II: Topical Studies in Oceanography》2009,56(18):1363-1368

The MedFlux project was devised to determine and model relationships between organic matter and mineral ballasts of sinking particulate matter in the ocean. Specifically we investigated the ballast ratio hypothesis, tested various commonly used sampling and modeling techniques, and developed new technologies that would allow better characterization of particle biogeochemistry. Here we describe the rationale for the project, the biogeochemical provenance of the DYFAMED site, the international support structure, and highlights from the papers published here. Additional MedFlux papers can be accessed at the MedFlux web site (http://msrc.sunysb.edu/MedFlux/).  相似文献