⁴⁰Ar/³⁹Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece     

M. BRÖCKER  H. KREUZER  A. MATTHEWS  M. OKRUSCH 《Journal of Metamorphic Geology》1993,11(2):223-240

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.  相似文献   

The middle pleistocene deposits of Waverley Wood Pit,Warwickshire, England     

F. W. Shotton  D. H. Keen  G. R. Coope  A. P. Currant  P. L. Gibbard  M. Aalto  S. M. Peglar  J. E. Robinson 《第四纪科学杂志》1993,8(4):293-325

A complex of channels underlying the Baginton-Lillington Gravel (Baginton Formation) at Waverley Wood Quarry, Warwickshire is described. Fossil pollen and plant macrofossils, Coleoptera, Ostracoda, Mollusca and Mammalia are described from the channel-fill deposits. Consideration of all the evidence allows the identification of four separate stages of channel fill which largely occurred under a cool temperate climate. At the top of Channel 2 evidence for a cold, continental climatic episode can be recognised, suggesting that the whole complex was deposited under a fluctuating climate at the end of a temperate stage. At two levels in the channels human artefacts were recovered confirming the presence of Palaeolithic people in Warwickshire during the deposition of the sediments. Amino-acid geochronology suggests an age within the ‘Cromerian Complex’ Stage for the channels. The small vertebrate and molluscan faunas indicate that the deposits are no older than the latter part of the ‘Cromerian Complex’ Stage of East Anglia. The regional stratigraphic significance of the Waverley Wood succession is outlined.  相似文献   

Re-Os geochronology of Cu and W-Mo deposits in the Balkhash metallogenic belt,Kazakhstan and its geological significance   总被引：2，自引：0，他引：2  

Xuanhua Chen  Wenjun Qu  Shuqin Han  Seitmuratova Eleonora  Nong Yang  Zhengle Chen  Fagang Zeng  Andao Du  Zhihong Wang 《地学前缘(英文版)》2010,1(1)

<正>The Central Asian metallogenic domain(CAMD) is a multi-core metallogenic system controlled by boundary strike-slip fault systems.The Balkhash metallogenic belt in Kazakhstan,in which occur many large and super-large porphyritic Cu—Mo deposits and some quartz vein- and greisen-type W—Mo deposits,is a well-known porphyritic Cu—Mo metallogenic belt in the CAMD.In this paper 11 molybdenite samples from the western segment of the Balkhash metallogenic belt are selected for Re—Os compositional analyses and Re—Os isotopic dating.Molybdenites from the Borly porphyry Cu deposit and the three quartz vein-greisen W—Mo deposits—East Kounrad.Akshatau and Zhanet—all have relatively high Re contents(2712—2772μg/g for Borly and 2.267—31.50μg/g for the other three W—Mo deposits),and lower common Os contents(0.670—2.696 ng/g for Borly and 0.0051—0.056 ng/g for the other three).The molybdenites from the Borly porphyry Cu—Mo deposit and the East Kounrad,Zhanet,and Akshatau quartz vein- and greisen-type W—Mo deposits give average model Re—Os ages of 315.9 Ma,298.0 Ma,295.0 Ma,and 289.3 Ma respectively.Meanwhile,molybdenites from the East Kounrad,Zhanet,and Akshatau W—Mo deposits give a Re—Os isochron age of 297.9 Ma,with an MSWD value of 0.97.Re-Os dating of the molybdenites indicates that Cu—W—Mo metallogenesis in the western Balkhash metallogenic belt occurred during Late Carboniferous to Early Permian(315.9—289.3 Ma),while the porphyry Cu—Mo deposits formed at—316 Ma,and the quartz vein-greisen W—Mo deposits formed at ~298 Ma.The Re—Os model and isochron ages thus suggest that Late Carboniferous porphyry granitoid and pegmatite magmatism took place during the late Hercynian movement.Compared to the Junggar-East Tianshan porphyry Cu metallogenic belt in northwestern China,the formation of the Cu—Mo metallogenesis in the Balkhash metallogenic belt occurred between that of the Tuwu-Yandong in East Tianshan and the Baogutu porphyry Cu deposits in West Junggar. Collectively,the large-scale Late Carboniferous porphyry Cu—Mo metallogenesis in the Central Asian metallogenic domain is related to Hercynian tectono-magmatic activities.  相似文献   

  总被引：2，自引：0，他引：2  

Jesse B. Walters  Matthew J. Kohn 《Journal of Metamorphic Geology》2017,35(8):897-917

The Greater Himalayan Sequence (GHS) has commonly been treated as a large coherently deforming high‐grade tectonic package, exhumed primarily by simultaneous thrust‐ and normal‐sense shearing on its bounding structures and erosion along its frontal exposure. A new paradigm, developed over the past decade, suggests that the GHS is not a single high‐grade lithotectonic unit, but consists of in‐sequence thrust sheets. In this study, we examine this concept in central Nepal by integrating temperature–time (T–t) paths, based on coupled Zr‐in‐titanite thermometry and U–Pb geochronology for upper GHS calcsilicates, with traditional thermobarometry, textural relationships and field mapping. Peak Zr‐in‐titanite temperatures are 760–850°C at 10–13 kbar, and U–Pb ages of titanite range from c. 30 to c. 15 Ma. Sector zoning of Zr and distribution of U–Pb ages within titanite suggest that diffusion rates of Zr and Pb are slower than experimentally determined rates, and these systems remain unaffected into the lower granulite facies. Two types of T–t paths occur across the Chame Shear Zone (CSZ). Between c. 25 and 17–16 Ma, hangingwall rocks cool at rates of 1–10°C/Ma, while footwall rocks heat at rates of 1–10°C/Ma. Over the same interval, temperatures increase structurally upwards through the hangingwall, but by 17–16 Ma temperatures converge. In contrast, temperatures decrease upwards in footwall rocks at all times. While the footwall is interpreted as an intact, structurally upright section, the thermometric inversion within the hangingwall suggests thrusting of hotter rocks over colder from c. 25 to c. 17–16 Ma. Retrograde hydration that is restricted to the hangingwall, and a lithological repetition of orthogneiss are consistent with thrust‐sense shear on the CSZ. The CSZ is structurally higher than previously identified intra‐GHS thrusts in central Nepal, and thrusting duration was 3–6 Ma longer than proposed for other intra‐GHS thrusts in this region. Cooling rates for both the hangingwall and footwall of the CSZ are comparable to or faster than rates for other intra‐GHS thrust sheets in Nepal. The overlap in high‐T titanite U–Pb ages and previously published muscovite ⁴⁰Ar/³⁹Ar cooling ages imply cooling rates for the hangingwall of ≥200°C/Ma after thrusting. Causes of rapid cooling include passive exhumation driven by a combination of duplexing in the Lesser Himalayan Sequence, and juxtaposition of cooler rocks on top of the GHS by the STDS. Normal‐sense displacement does not appear to affect T–t paths for rocks immediately below the STDS prior to 17–16 Ma.  相似文献   

U–Pb dating of silicic lavas,sills and syneruptive resedimented volcaniclastic deposits of the Lower Devonian Crudine Group,Hill End Trough,New South Wales     

E. A. Jagodzinski  L. P. Black 《Australian Journal of Earth Sciences》2013,60(5):749-764

The Hill End Trough of central‐western New South Wales was an elongate deep marine basin that existed in the Lachlan Fold Belt from the early Late Silurian to late Early Devonian. It is represented by a regionally extensive, unfossiliferous sequence of interbedded turbidites and hemipelagites of substantially silicic volcanic derivation, which passes laterally into contemporaneous shallow‐water sedimentary rocks. The Turondale and Merrions Formations of the Lower Devonian Crudine Group are two prominent volcanogenic formations in the predominantly sedimentary trough sequence. They contain a range of primary and resedimented volcanic facies suitable for U–Pb dating. These include widespread subaqueous silicic lavas and/or lava cryptodomes, and thick sequences of crystal‐rich volcaniclastic sandstone emplaced by a succession of mass‐flows that were generated by interaction between contemporaneous subaerial pyroclastic flows and the sea. Ion microprobe dating of the two volcanogenic formations by means of the commonly used SL 13 zircon standard yields ages ranging between 411.3 ± 5.1 and 404.8 ± 4.8 Ma. Normalising the data against a different zircon standard (QGNG) yields preferred slightly older mean ages that range between 413.4 ± 6.6 and 407.1 ± 6.9 Ma. These ages broadly approximate the Early Devonian age that has been historically associated with the Crudine Group. However, the biostratigraphically inferred late Lochkovian ‐ early Emsian (mid‐Early Devonian) age for the Merrions Formation is inconsistent with the current Australian Phanerozoic Timescale, which assigns an age of 410 Ma to the Silurian‐Devonian boundary, and ages of 404.5 Ma and 395.5 Ma to the base and top of the Pragian, respectively. There is, however, good agreement if the new ages are compared with the most recently published revision of the Devonian time‐scale. This suggests that the Early Devonian stage boundaries of the Australian Phanerozoic Timescale need to be revised downward. The new ages for the Merrions Formation could also provide a time point on this time‐scale for the Pragian to early Emsian, for which no data are presently available.  相似文献   

    

Etienne Deloule 《Geostandards and Geoanalytical Research》2006,30(3):175-182

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.  相似文献   

  总被引：1，自引：0，他引：1  

HEAMAN  LARRY M.; CREASER  ROBERT A.; COOKENBOO  HARRISON O.; CHACKO  TOM 《Journal of Petrology》2006,47(4):821-858

The Jericho kimberlites are part of a small Jurassic kimberlitecluster in the northern Slave craton, Canada. A variety of datingtechniques were applied to constrain the nature and age of twoJericho kimberlites, JD-1 (170·2 ± 4·3Ma Rb–Sr phlogopite megacrysts, 172·8 ±0·7 Ma U–Pb eclogite rutile, 178 ± 5 MaU–Pb eclogite zircon lower intercept) and JD-3 (173 ±2 Ma Rb–Sr phlogopite megacryst; 176·6 ±3·2 Ma U–Pb perovskite), and all yielded identicalresults within analytical uncertainty. As there is no discernibledifference in the radiometric ages obtained for these two pipes,the composite Rb–Sr phlogopite megacryst date of 173·1± 1·3 Ma is interpreted as the best estimate forthe emplacement age of both Jericho pipes. The initial Sr isotopecomposition of 0·7053 ± 0·0003 derivedfrom phlogopite megacrysts overlaps the range (0·7043–0·7084)previously reported for Jericho whole-rocks. These strontiumisotope data, combined with the radiogenic initial ²⁰⁶Pb/²⁰⁴Pbratio of 18·99 ± 0·33 obtained in thisstudy, indicate that the Jericho kimberlites are isotopicallysimilar to Group 1 kimberlites as defined in southern Africa.The Jericho kimberlites are an important new source of mantlexenoliths that hold clues to the nature of the Slave cratonsubcontinental mantle. A high proportion (30%) of the Jerichomantle xenolith population consists of various eclogite typesincluding a small number (2–3%) of apatite-, diamond-,kyanite- and zircon-bearing eclogites. The most striking aspectof the Jericho zircon-bearing eclogite xenoliths is their peculiargeochemistry. Reconstructed whole-rock compositions indicatethat they were derived from protoliths with high FeO, Al₂O₃and Na₂O contents, reflected in the high-FeO (22·6–27·5wt %) nature of garnet and the high-Na₂O (8·47–9·44wt %) and high-Al₂O₃ (13·12–14·33 wt %)character of the clinopyroxene. These eclogite whole-rock compositionsare highly enriched in high field strength elements (HFSE) suchas Nb (133–1134 ppm), Ta (5–28 ppm), Zr (1779–4934ppm) and Hf (23–64 ppm). This HFSE enrichment is linkedto growth of large (up to 2 mm) zircon and niobian rutile crystals(up to 3 modal %) near the time of eclogite metamorphism. Thediamond-bearing eclogites on the other hand are characterizedby high-MgO (19·6–21·3 wt %) garnet andultralow-Na₂O (0·44–1·50 wt %) clinopyroxene.Paleotemperature estimates indicate that both the zircon- anddiamond-bearing eclogites have similar equilibration temperaturesof 950–1020°C and 990–1030°C, respectively,corresponding to mantle depths of 150–180 km. Integrationof petrographic, whole-rock and mineral geochemistry, geochronologyand isotope tracer techniques indicates that the Jericho zircon-bearingeclogite xenoliths have had a complex history involving Paleoproterozoicmetamorphism, thermal perturbations, and two or more episodesof Precambrian mantle metasomatism. The oldest metasomatic event(Type 1) occurred near the time of Paleoproterozoic metamorphism(1·8 Ga) and is responsible for the extreme HFSE enrichmentand growth of zircon and high-niobian rutile. A second thermalperturbation and concomitant carbonatite metasomatism (Type2) is responsible for significant apatite growth in some xenolithsand profound light rare earth element enrichment. Type 2 metasomatismoccurred in the period 1·0–1·3 Ga and isrecorded by relatively consistent whole-rock eclogite modelNd ages and secondary U–Pb zircon upper intercept dates.These eclogite xenoliths were derived from a variety of protoliths,some of which could represent metasomatized pieces of oceaniccrust, possibly linked to east-dipping subduction beneath theSlave craton during construction of the 1·88–1·84Ga Great Bear continental arc. Others, including the diamond-bearingeclogites, could be cumulates from mafic or ultramafic sillcomplexes that intruded the Slave lithospheric mantle at depthsof about 150–180 km. KEY WORDS: zircon- and diamond-bearing eclogites; Jericho kimberlite, geochronology; Precambrian metasomatism, northern Slave Craton  相似文献   

    

《Journal of South American Earth Sciences》2015

The Sergipano belt is the outcome of collision between the Pernambuco-Alagoas Domain (Massif) and the São Francisco Craton during Neoproterozoic assembly of West Gondwana. Although the understanding of the Sergipano belt evolution has improved significantly, the timing of emplacement, geochemistry and tectonic setting of granitic bodies in the belt is poorly known. We recognized two granite age groups: 630–618 Ma granites in the Canindé, Poço Redondo and Macururé domains, and 590–570 Ma granites in the Macururé metasedimentary domain. U–Pb SHRIMP zircon ages for granites of first age group indicated ages of 631 ± 4 Ma for the Sítios Novos granite, 623 ± 7 Ma for the Poço Redondo granite, 619 ± 3.3 Ma for the Lajedinho monzodiorite, and 618 ± 3 Ma for the Queimada Grande granodiorite. These granitoids are dominantly high-K calc-alkaline, magnesian, metaluminous, mafic enclave-rich (Queimada Grande and Lajedinho), or with abundant inherited zircon grains (Poço Redondo and Sitios Novos). Geochemical and isotope data allow us to propose that Sítios Novos and Poço Redondo granites are product of partial melting of Poço Redondo migmatites. Sr-Nd isotopes of the Queimada Grande granodiorite and Lajedinho monzodiorite suggest that their parental magma may have originated by mixing between a juvenile mafic source and a crustal component that could be the Poço Redondo migmatites or the Macururé metasediments. Other 630–618 Ma granites in the belt are the mafic enclave-rich Coronel João Sá granodiorite and the Camará tonalite in the Macururé sedimentary domain. These granites have similar geochemical and isotopic characteristics as the Lajedinho and Queimada Grande granitoids. We infer for the Camará tonalite and Coronel João Sá granodiorite that their parental magmas have had contributions from mafic lower crust and felsic upper crust, most probably from underthrust São Francisco Craton, or Pernambuco-Alagoas Domain. The younger 590–570 Ma granite group is confined to the Macururé metasedimentary domain. Although these granites do not show typical features of S-type granites, their U–Pb age, field relationships, geochemical and Sr-Nd data suggest that their parental magmas have originated from high degree melting of the Macururé micaschists. Field observations support a model in which the Macururé domain, limited by the Belo Monte-Jeremoabo and São Miguel do Aleixo shear zones, behaved as a ductile channel flow for magma migration and emplacement during the Neoproterozoic, very much like the channel flow model proposed for emplacement of leucogranites in the Himalayas.  相似文献   

Geological and SHRIMP II U-Pb constraints on the age and origin of the Breves Cu-Au-(W-Bi-Sn) deposit,Carajás,Brazil     

Fernando?Henrique?Bucco?TallaricoEmail author  Neal?Jesse?McNaughton  David?Ian?Groves  Ian?R.?Fletcher  Bernardino?Ribeiro?Figueiredo  Jéssica?Beatriz?Carvalho  José?Luzimar?Rego  Alfredo?Rossetto?Nunes 《Mineralium Deposita》2004,39(1):68-86

The Breves deposit in the Carajás Copper-Gold Belt, Brazil, a member of the Cu-Au-(W-Bi-Sn) group of deposits, contains about 50 Mt of 1.22% Cu, 0.75 g/t Au, 2.4 g/t Ag, 1,200 g/t W, 70 g/t Sn, 175 g/t Mo and 75 g/t Bi. It is hosted by sandstones and siltstones of the Águas Claras Formation (minimum age of 2,681±5 Ma) in the roof zone of a complex, highly altered granite intrusion. The mineralisation is disseminated in a greisenized zone, resulting from alteration of probable monzogranites and syenogranites. The ore-bearing greisen contains abundant xenomorphic quartz in association with Fe-chlorite and muscovite. The gangue assemblage also includes fluorite, tourmaline, and minor amounts of monazite, xenotime, chlorapatite, thorite, zircon, calcite, siderite and bastnäesite. Copper mineralisation is dominated by chalcopyrite associated with pyrite, arsenopyrite, pyrrhotite and molybdenite. Gold particles, in equilibrium with native bismuth, are common as inclusions in chalcopyrite. The greisen contains sub-economic concentrations of tungsten and niobium that are related to the presence of ferberite, qitianlingite and Nb-rutile. SHRIMP II zircon dating of the host granites gives ²⁰⁷Pb/²⁰⁶Pb ages of 1,878±8 and 1,880±9 Ma for two phases, and a combined age of 1,879±6 Ma. SHRIMP II dating of monazite and xenotime grains in late- to post-mineralisation veins gives a combined ²⁰⁷Pb/²⁰⁶Pb age of 1,872±7 Ma, indistinguishable from the ages of the granites. This provides a genetic connection between the Breves deposit and the ca. 1.88 Ga A-type granite magmatism that typifies the Carajás Belt as part of a much larger, intracratonic magmatic province that extends over much of the Amazonian Craton. The recognition of this association has exploration implications, not only for the geophysical signature of the granite roof zones, but also for likely geochemical dispersion around the deposits of this type.Editorial handling: G. Beaudoin  相似文献   

    

《Geological Journal》2018,53(4):1573-1585

The tectonic/stratigraphic interpretation of the Cambro–Ordovician rocks exposed in the south‐westernmost sectors of the Sardinia island (i.e., belonging to the Bithia Formation or Unit) is still a hot point of discussion. A debated question is also the age of the metavolcanics interbedded in these rocks. In order to provide a clear answer to this problem, in this paper, we provide new U–Pb zircon dating and a petrographic–geochemical comparison of metavolcanics interbedded within the Bithia Formation with similar Sardinian Ordovician calc‐alkaline rocks. The Bithia metavolcanics plot in the rhyodacite/rhyolite field. They show negative troughs for Nb and Ta, negative anomalies for Sr, P, and Ti, and positive peaks for Cs, Rb, K, Th, U, and Pb in the multielement diagram normalized to primitive mantle and significant LREE enrichment, marked negative Eu anomaly, and flat HREE patterns in the chondrite‐normalized REE diagram. Owing to these geochemical features, the Bithia metavolcanics plot in the volcanic arc and active continental margin fields closely resembling Middle‐Late Ordovician felsic metavolcanics from the Sarrabus, Gerrei, Goceano, and Mt. Grighini units. A new U–Pb zircon age of 462.1 ± 4.3 Ma yielded by a metavolcanic layer within the Bithia Formation at Capo Malfatano must be interpreted as the emplacement age. The CL and BSE images of zircon grains do not show any evidence of interaction with late hydrothermal fluids that could have caused Pb loss and rejuvenated ages, confirming the Middle‐Late Ordovician age of the metavolcanics.  相似文献