Fire and ice: unravelling the climatic and volcanic history of James Ross Island, Antarctic Peninsula     

John Smellie  Anna Nelson  Mark Williams 《Geology Today》2006,22(6):220-226

Back in the mid-nineteenth century British explorer James Clark Ross took his ships, HMS Terror and HMS Erebus , farther south than anyone else had been. He now lends his name to James Ross Island, a part-volcanic edifice that rises out of the sea off the north-east tip of the Antarctic Peninsula. The island records a geological history dating back to the Cretaceous, though its great peaks are volcanic. The most recent rocks of the island record a monumental struggle between fire and ice, the volcanoes, and the ice sheets that cover them. The glacigenic sediments that are interspersed with the volcanic rocks contain rich fossil assemblages which suggest that at times, the climate was warmer, with the ice retreating. Their study may help us to delimit the patterns of climate change in the Antarctic Peninsula region as Earth's global climate warms.  相似文献   

Coulometric TCO2 analyses for marine studies; an introduction     

Kenneth M Johnson  Arthur E King  John McN Sieburth 《Marine Chemistry》1985,16(1):61-82

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.  相似文献   

Kinetic studies of lead(II) uptake by the seagrass Zostera muelleri in water by radiotracing,atomic absorption spectrometry and electrochemical techniques     

Alan M Bond  Julie R Bradbury  Henry A Hudson  John S Garnham  Peter J Hanna  Stanley Strother 《Marine Chemistry》1985,16(1):1-9

Evidence was found that uptake of lead from seawater in both model and natural systems by the leaves of the seagrass Zostera muelleri does occur for live, dead and scraped leaves at all the lead concentrations tested. Positive uptake of lead was measured using the three analytical techniques of radio-tracer, differential pulse anodic stripping voltammetry and atomic absorption spectrometry; similar uptake profiles were obtained for each technique. Profiles always showed an initial rapid uptake phase followed by a gradual transition to a plateau phase at which an approximate equilibrium between lead attached to seagrass and free ionic lead in seawater was reached. The presence of active lead uptake processes was indicated in experiments which attempted to remove lead from leaves by a chelating agent.  相似文献   

A plea for precision inMathematical Geology     

John Aitchison 《Mathematical Geology》1991,23(8):1081-1083

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Nitrogen uptake,ammonium oxidation and nitrous oxide (N₂O) levels in the coastal waters of western Cook Strait,New Zealand     

John C. Priscu  Malcolm T. Downes 《Estuarine, Coastal and Shelf Science》1985,20(5):529-542

Vertical measurements of $\text{NH}{}_4{}^{\mathrm{+}}$, $\text{NO}{}_3{}^{\mathrm{?}}$ and N₂O concentrations, $\text{NO}{}_3{}^{\mathrm{?}}$ and $\text{NH}{}_4{}^{\mathrm{+}}$ uptake, and $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation rates were measured at 5 sites in western Cook Strait, New Zealand, between 31 March and 3 April 1983. Nitrate increased with depth at all stations reaching a maximum of 10.5 μg-atom $\text{NO}{}_3{}^{\mathrm{?}}\text{N l}{}^{\mathrm{?1}}$ at the most strongly stratified station whereas $\text{NH}{}_4{}^{\mathrm{+}}$ was relatively constant with depth at all stations (～0.1 μg-atom $\text{NH}{}_4{}^{\mathrm{+}}\text{N l}{}^{\mathrm{?1}}$). The highest rates of $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation generally occurred in the near surface waters and decreased with depth. N₂O levels were near saturation with respect to the air above the sea surface and showed no obvious changes during 24 h incubation. $\text{NH}{}_4{}^{\mathrm{+}}$ oxidation by nitrifying bacteria may account for about 30% of the total $\text{NH}{}_4{}^{\mathrm{+}}$ utilization (i.e. bacterial+agal) and, assuming oxidation through to $\text{NO}{}_3{}^{\mathrm{?}}$, may supply about 40% of the algal requirements of $\text{NO}{}_3{}^{\mathrm{?}}$ in the study area. These results suggest that bacterial nitrification is of potential importance to the nitrogen dynamics of the western Cook Strait, particularly with respect to the nitrogen demands of the phytoplankton.  相似文献   

Volcanoes and the environment     

Dr. John Cobbing 《《幕》》2006,29(1):71-71

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Oxygen isotope study of the Long Valley magma system, California: isotope thermometry and convection in large silicic magma bodies   总被引：1，自引：0，他引：1  

Ilya N. Bindeman  John W. Valley 《Contributions to Mineralogy and Petrology》2002,144(2):185-205

Products of voluminous pyroclastic eruptions with eruptive draw-down of several kilometers provide a snap-shot view of batholith-scale magma chambers, and quench pre-eruptive isotopic fractionations (i.e., temperatures) between minerals. We report analyses of oxygen isotope ratio in individual quartz phenocrysts and concentrates of magnetite, pyroxene, and zircon from individual pumice clasts of ignimbrite and fall units of caldera-forming 0.76 Ma Bishop Tuff (BT), pre-caldera Glass Mountain (2.1-0.78 Ma), and post-caldera rhyolites (0.65-0.04 Ma) to characterize the long-lived, batholith-scale magma chamber beneath Long Valley Caldera in California. Values of '¹⁸O show a subtle 1‰ decrease from the oldest Glass Mountain lavas to the youngest post-caldera rhyolites. Older Glass Mountain lavas exhibit larger (~1‰) variability of '¹⁸O(quartz). The youngest domes of Glass Mountain are similar to BT in '¹⁸O(quartz) values and reflect convective homogenization during formation of BT magma chamber surrounded by extremely heterogeneous country rocks (ranging from 2 to +29‰). Oxygen isotope thermometry of BT confirms a temperature gradient between "Late" (815 °C) and "Early" (715 °C) BT. The '¹⁸O(quartz) values of "Early" and "Late" BT are +8.33 and 8.21‰, consistent with a constant '¹⁸O(melt)=7.8ǂ.1‰ and 100 °C temperature difference. Zircon-melt saturation equilibria gives a similar temperature range. Values of '¹⁸O(quartz) for different stratigraphic units of BT, and in pumice clasts ranging in pre-eruptive depths from 6 to 11 km (based on melt inclusions), and document vertical and lateral homogeneity of '¹⁸O(melt). Worldwide, five other large-volume rhyolites, Lava Creek, Lower Bandelier, Fish Canyon, Cerro Galan, and Toba, exhibit equal '¹⁸O(melt) values of earlier and later erupted portions in each of the these climactic caldera-forming eruptions. We interpret the large-scale '¹⁸O homogeneity of BT and other large magma chambers as evidence of their longevity (>10⁵ years) and convection. However, remaining isotopic zoning in some quartz phenocrysts, trace element gradients in feldspars, and quartz and zircon crystal size distributions are more consistent with far shorter timescales (10²-10⁴ years). We propose a sidewall-crystallization model that promotes convective homogenization, roofward accumulation of more evolved and stagnant, volatile-rich liquid, and develops compositional and temperature gradients in pre-climactic magma chamber. Crystal + melt + gas bubbles mush near chamber walls of variable '¹⁸O gets periodically remobilized in response to chamber refill by new hotter magmas. One such episode of chamber refill by high-Ti, Sr, Ba, Zr, and volatile-richer magma happened 10³-10⁴ years prior to the 0.76-Ma caldera collapse that caused magma mixing at the base, mush thawing near the roof and walls, and downward settling of phenocrysts into this hybrid melt.  相似文献   

Comment on “Resuspension of urban soils as a persistent source of lead poisoning in children: A review and new directions” by Laidlaw M.A.S. and Filipelli G.M.     

John D. Bogden  Francis W. Kemp 《Applied Geochemistry》2009

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The pattern of Ni and Co abundances in lunar olivines     

John Longhi  Sedelia R. Durand  David Walker 《Geochimica et cosmochimica acta》2010,74(2):784-3045

Near liquidus experiments on peridotite and other olivine normative compositions from 1.7 to 6 GPa confirm the applicability of exchange-based empirical models of Ni and Co partitioning between olivine and silicate liquids with compositions close to the liquidus of peridotite. Given that most estimates of lunar bulk composition are peridotitic, the partitioning models thus lend themselves to calculation of olivine compositions produced during the early stages of magma ocean crystallization. Calculation of olivine compositions produced by fractional crystallization of a model lunar magma ocean, initially 700 km deep, reveals a prominent maximum in Ni concentration versus fraction crystallized or Mg’ (molar MgO/(MgO + FeO)), but a pattern of monotonically increasing Co concentration. These patterns qualitatively match the puzzling patterns of Ni and Co concentrations observed in lunar rocks in which forsteritic olivines in magnesian suite cumulates have lower Ni and Co abundances than do less magnesian olivines from low-Ti mare basalts, and olivines from the ferroan anorthosite suite (FAS) have lower Ni, but similar Co to mare basalt olivines.The Ni and Co abundances in olivines from the magnesian suite cumulates can be reconciled in terms of fractional crystallization of a deep magma ocean which initially produces a basal dunite comprised of the hottest and most magnesian olivine overlain by an olivine-orthopyroxene (harzburgite) layer that is in turn overlain by an upper zone of plagioclase-bearing cumulates. The ultramafic portion of the cumulate pile overturns sending the denser harzburgite layer, which later becomes a portion of the green glass source region, to the bottom of the cumulate pile with Ni- and Co-rich olivine. Meanwhile, the less dense, but hottest, most magnesian olivines with much lower Ni and Co abundances are transported upward to the base of the plagioclase-bearing cumulates where subsequent heat transfer leads to melting of mixtures of primary dunite, norite, and gabbronorite with KREEP (a K-REE-P enriched component widely believed to be derived from the very latest stage magma ocean liquid). These hybrid melts have Al₂O₃, Ni, and Co abundances and Mg’ appropriate for parent magmas of the magnesian suite. Ni and Co abundances in the FAS are consistent with either direct crystallization from the magma ocean or crystallization of melts of primary dunite-norite mixtures without KREEP.  相似文献   

    

Sheila J Seaman  William C McIntosh  John W Geissman  Michael L Williams  Wolfgan E Elston 《Bulletin of Volcanology》1991,53(6):460-476

Anisotropy of magnetic susceptibility (AMS) of the middle Tertiary Bloodgood Canyon and Shelley Peak Tuffs of the Mogollon-Datil volcanic field has been used to (1) evaluate the ability of AMS to constrain flow lineations in low-susceptibility ash-flow tuffs; (2) establish a correlation between magnetic fabric, magnetic mineralogy, tuff facies, and characteristics of the depositional setting; and (3) constrain source locations of the tuffs. The tuffs are associated with the overlapping Bursum caldera and Gila Cliff Dwellings basin. The high-silica Bloodgood Canyon Tuff fills the Gila Cliff Dwellings basin and occurs as thin outcrops outside of the basin. The older Shelley Peak Tuff occurs as thin outcrops both along the boundary between the two structures, and outside of the complex. AMS data were collected from 16 sites of Bloodgood Canyon Tuff basin fill, 19 sites of Bloodgood Canyon Tuff outflow, and 11 sites of Shelley Peak Tuff. Sites were classified on the basis of within-site clustering of orientations of principal susceptibility axes, based on the categories of Knight et al. (1986). Most microscopically visible oxide minerals in the Bloodgood Canyon Tuff outflow and basin fill, and in the Shelley Peak Tuff are members of the hematite-ilmenite solid solution series. However, IRM acquisition data indicate that Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff have magnetic mineralogy dominated by single- or pseudo-single-domain magnetite, and that the magnetic mineralogy of the Bloodgood Canyon Tuff outflow is dominated by hematite. Hematite in Bloodgood Canyon Tuff outflow is likely to be the result of deuteric and/or low-temperature alteration of magnetite and iron silicate minerals. Bulk magnetic susceptibility is higher in magnetite-dominated ash-flow tuff (Bloodgood Canyon Tuff basin fill and Shelley Peak Tuff) than it is in hematite-dominated ash-flow tuff (Bloodgood Canyon Tuff outflow). Bloodgood Canyon Tuff outflow has the highest total anisotropy (H) of the three units, followed by Shelley Peak Tuff and Bloodgood Canyon Tuff basin fill. All three ash-flow tuffs are genearlly characterized by oblate susceptibility ellipsoids, with those of the Bloodgood Canyon Tuff basin fill nearest to spherical. At high values of total anisotropy, Shelley Peak Tuff susceptibility ellipsoids attain a prolate shape; those of Bloodgood Canyon Tuff outflow attain an increasingly oblate shape. Three factors may influence differences in total anisotropy and susceptibility ellipsoid shape: (1) ash which travelled the greatest distance before deposition may show the best development of magnetic fabric, particularly of magnetic lineation; (2) deposition of ash in a closed basin may inhibit laminar flow throughout the sheet and the resulting development of flow textures; and (3) replacement of magnetite and iron silicates preferentially oriented within the foliation plane by hematite with strong crystalline anisotropy may enhance the magnetic susceptibility within that plane. Scatter in AMS axis orientation within sites may result from: (1) greater orientation inaccuracy in block-sampled than in fielddrilled samples; (2) rheomorphism; and (3) low accuracy of AMS measurement in low-susceptibility ashflow tuffs. Evaluation of flow lineation based on AMS of sites with well-clustered K₁ axes indicates that (1) Bloodgood Canyon Tuff basin fill flowed along a generally northwest-southeast azimuth; (2) Shelley Peak Tuff located on the boundary of the Bursum caldera and the Gila Cliff Dwellings basin flowed along a nearly east-west azimuth; and (3) Bloodgood Canyon Tuff outflow sites have K₁ susceptibility axes generally radial to the Bursum-Gila Cliff Dwellings complex, but within-site scatter of K₁ orientations is generally too large to draw conclusions about flow lineation orientation. Limited petrographic work on pilot thin sections adds flow direction information to AMS-derived flow lineation information.  相似文献