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In the study of the history of deformed sedimentary rocks it is important that the cause of the deformation and the timing of deformation relative to metamorphic and tectonic events be assessed. There is a continuous gradation between the deformation of freshly deposited sediments by gravitational forces and the deformation of well-lithified sediments by tectonic forces, so determining the degree to which gravity, tectonism and lithification influenced deformation can be very difficult. The characteristics that may be considered in determining the origin of deformational structures in sedimentary rocks can be divided into five categories: Ductile deformation structures (1) can provide definitive criteria for recognizing post-lithification deformation, but not pre-lithification deformation. This also holds for (2), brittle deformation structures and décollements. Overprinting of sediment reworking or remobilization structures (3) are the best criteria for recognizing pre-lithification structures. Fabrics (4) can be very useful but are as yet poorly understood, and there are misconceptions in the literature about what sort of fabrics are or are not found in unlithified sediments. Spatial relationships (5) may also tell us a great deal, but are most useful when taken in conjunction with other types of evidence.Complex fold patterns in sandstones on Farmer Head, north-central Newfoundland, provide a case study for criteria that may be used to determine the degree of lithification during deformation. Although these folds have been interpreted as slump folds by earlier workers, fabrics and spatial relationships point to a tectonic post-lithification origin for the structures, a conclusion which has significant implications for the interpretation of the regional geology.  相似文献   
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《Applied Geochemistry》2002,17(4):353-365
Surprisingly little is known about the relationship between the labile phases removed by sequential extraction procedures and those liberated by single leaches that minimally impact the alumino-silicate matrix of solids. This investigation examines the relationship between the summed concentrations of Al, Co, Cu, Fe, Mn, Ni, Pb and Zn released by an optimized 3-step standardized sequential extraction procedure and those released by a single 0.5 M HCl leach. Thirty-nine representative soil and road deposited sediment samples were examined from an urban watershed, in Honolulu, Hawaii, which has been shown to have a high degree of traffic-associated pollution. Properties of samples analyzed varied widely and exhibited a range in cation exchange capacities from 7 to 59 cmolc/kg, pH values from 3.5 to 7.9, and organic C contents from 1 to 29%. Results indicate that the dilute HCl leach was slightly more aggressive than the sequential procedure as it removed significantly more Al, Cu, Fe, Mn and Ni; though no significant differences were observed between Co, Pb and Zn concentrations liberated by the two approaches. Both approaches showed limited dissolution of the crystal lattice with ⩽9% of the total Al liberated. Regardless of approach, element mobility was the same with the order being: Pb>Mn>Zn>Co≈Cu>Ni>Fe ∼ Al. Regression analysis indicated highly significant (P<0.0001) logarithmic relationships between the two digestion procedures, with coefficients of determination (r2) ⩾92% for all elements except Fe (54%) and Ni (64%). Further support for the strong relationships between elements liberated by both digestions was gained from geochemical contrasts between anomalous and background levels and concentration enrichment ratios. This was particularly true for Pb and Zn, the most anthropogenically enhanced trace metals in the watershed. All data indicated that a dilute HCl leach was a valuable, rapid, and cost-effective analytical tool in contamination assessment.  相似文献   
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The unclear understanding of the source rock characteristics for the Paleogene Dongying Formation in the Bozhong Sag leads to the lack of cognition in oil and gas exploration. This research systematically evaluated the discrepancy in geochemical characteristics of source rock intervals in the Dongying Formation based on detailed analysis using Rock-Eval pyrolysis, total organic carbon (TOC), vitrinite reflectance (Ro), maceral components, stable carbon isotopes and biomarker parameters. It discusses the organic matter sources, depositional environment, thermal maturity and hydrocarbon generation potential in the source rock intervals of the Dongying Formation. The organic matter abundance in the third member (E3d3) and lower sub-member of the second member (E3d2L) of the Dongying Formation is higher, with an average TOC of 2.08% and 1.03%, respectively, indicating that these source rock intervals could have good and excellent quality. The source rocks of the Dongying Formation predominately contain exinite maceral group and type II1 and II2 kerogen. The thermal evolution is mainly in the low-mature and mature stages. The organic matter sources in the Dongying Formation are mainly dominated by mixed origin (the carbon isotope reversal of aromatics also provides a potential explanation). However, the values of 1,2,5−/1,3,6-trimethylnaphthalene, (1,2,5,6 + 1,2,3,5)-tetramethylnaphthalene/tetramethylnaphthalenes, methyldibenzofuran/methylphenanthrene (MDBF/MP) and dibenzofuran/phenanthrene (DBF/PHEN) parameters in the E3d3 and some samples in E3d2L decipher relatively smaller values than other source rock intervals, proving the enhancement of the contribution of lower organisms. Moreover, the terrestrial input in the bottom-up deposition process of the Dongying Formation gradually increases. The depositional environment reveals the Dongying Formation source rocks mainly developed freshwater sulphur-poor lacustrine facies and shallow lake-fluvial delta facies in an open clay-rich sedimentary environment with poor water column stratification, belonging to the typical weak oxidation–reduction depositional conditions. The comprehensive geochemical evaluation concludes that the favourable supply of lower organisms and stable clay-rich depositional environment in the E3d3 interval of the Dongying Formation are potential explanations for the formation of lacustrine source rocks with high organic matter abundance, intermediate thermal evolution and excellent hydrocarbon generation potential, providing a good foundation for the exploration and development prospects of hydrocarbons.  相似文献   
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The basal mudstones from the El-Nom borehole in the Gebel Abraq area in southern Egypt have yielded a diverse and relatively well preserved terrestrial palynoflora that includes Balmeisporites holodictyus, Crybelosporites pannuceus, Foveotricolpites gigantoreticulatus, Nyssapollenites albertensis, Retimonocolpites variplicatus and Rousea delicipollis. These suggest an Albian–Cenomanian age and deposition in a fluvio-deltaic environment; no marine phytoplankton is reported. The fern-dominated palynoflora and the overwhelming presence of kaolinitic clays suggest a warm, humid palaeoclimate. According to available knowledge, the mudstones in the Gebel Abraq area, equivalents of the so-called “Timsah Formation”, might be correlated with an older rock unit, the Maghrabi Formation, based on the new palynological age assessment. This new definition of local stratigraphy implies that the Bernice sheet of geological map of Egypt [Klitzsch, E., List, F., Pöhlmann, G., 1987. Geological map of Egypt, sheet NF 36 NE Bernice, 1: 500 000. Conoco and the Egyptian General Petroleum Corporation, Cairo] ought to be reconsidered.  相似文献   
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The rare gases were determined mass-spectrometrically in eleven unequilibrated ordinary chondrites. The amounts of primordial Ar, Kr and Xe are systematically greater than in ordinary chondrites proper. Primordial Ne was detected in only two of the meteorites. The amounts of the heavy rare gases Ar, Kr and Xe are approximately inversely proportional to the degree of equilibration of Fe in olivine, and are directly proportional to C contents. The primordial rare-gas contents of different pieces of Bishunpur, Krymka and Mezö-Madaras vary substantially, indicating that these meteorites are inhomogeneous in this respect. The heavy gases Ar, Kr and Xe are “planetary” in the sense of the model of Signer and Suess. The average primordial Ar86:Ar38 ratio of nine cases is 5.35 ± 0.16. Except for Xe129, the isotopic composition of Xe agrees with that of “average carbonaceous chondrites”. Carbonaceous chondrites, unequilibrated ordinary chondrites, and ordinary chondrites proper form a sequence of decreasing contents of primordial rare gases of the “planetary” type. This is consistent with a recent theory by Larimer and Anders on the formation of these meteorites. We infer from our results, however, that neon does not belong to the “planetary” component.  相似文献   
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Rock and mineral analyses should always be reported together with data obtained for rock and mineral standards analyzed with the unknowns. The problem of analytical accuracy may then be eliminated from geochemical comparison, Unless this is done, good analytical precision is lost from the point of view of such comparison.  相似文献   
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Sediment samples from the continental shelf and slope off Nova Scotia were fractionated with a combination of elutriation and sieving to investigate the most easily resuspended sediment fraction and thus processes of organic deposition. Bulk sediments on the slope were enriched in carbon and nitrogen compared to those on the shelf. Fractionation indicated that<40% of bulk particulate organic carbon (POC) and particulate organic nitrogen (PON) on the shelf (from a sandy bank and a muddy-sand basin) were readily resuspendable, reflecting the large proportion of sand at these stations. On the slope however, about 85% of the bulk POC and PON was resuspendable, due to the high silt-clay content. Resuspendable fractions at all stations did not differ significantly in organic content (i.e. richness). The similarity of these fine fractions, especially at basin and slope stations suggested a related origin (surface production) for these particles. The less resuspendable coarse fraction on the shelf was an organic-poor sand; on the slope the coarse fraction consisted of benthic fecal pellets, similar in richness to the fine fractions. Comparison of predicted and measured sedimentation rates suggested that enrichment of slope sediments could only be explained by horizontal transport of shelf production. This provides further support for the hypothesis that the continental slope is a sink in the global carbon budget.  相似文献   
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